By B. Mistry
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Extra info for A Handbook of Spectroscopic Data Chemistry : UV, IR, PMR, CNMR and Mass Spectroscopy
72 w. v. m. 33 s. v. ca. 1270 1260-1200 1257-1232 ca. 12 v. v. v. Phenols, tert. , fluorides Alkane, tert. butyl 'Alkane, geminal dimethyl, isopropyl, tert. butyl sym. CH 3 bending Alkane,-C~ C-H def. S=O str. C-H def. O-H def. O-H def. C-F str. C-H def. CH3 def. C-H def. Aliphatic nitro compounds Sulfonyl chlorides Nomatic nitro compounds Alkane, tert. butyl Aromatic tert. amines Sulfones, sulfonamides Aromatic sec. amines Prim. and sec. alcohols Alkanes Aromatic prim. amines Azides Sulfur compounds Alkene (R,CH=CHR2) trans Nitrates Conj.
87 d. Aryl p-anisaldehyde (CCI 4 ) CCI 4 Ketones (RCOR) a. 85 52 Spectroscopic Data Chemistry b. 99 h. 85 i. ~-Diketones (enolic) j. 92 c. a, ~- d. a, ~-Unsaturated, Unsaturated, acyclic Methyl vinyl ketone (CCI 4 ) cyclic acyclic f. Aryl propiophenone (CCI4 ) g. Diaryl Benzophenone (CHCI 3) k. Ketenes Amides a. 99 b. 97and c. ) 53 Infrarred Spectroscopy d. 95 e. 65 i. 02 j. 10 k. 85 f. Cyclic, y-Iactams, fused to another ring, dilute solution g. Cyclic, ~-Iactams, dilute solution h. Cyclic, ~-lactams, fused to another ring, dilute solution 1.
1260 Ca. 94 v. -so Si-C str. -s. sym. =symmetric s=strong absorption w=weak absorption def. 86 v. , sh. sh. Alcohols, phenols, free OH O-H str. Oximes (R-C = NOH) O-H str. R-OH, Ar-OH, intramolecular hydrogen bonded O-H str. 86 m. • sh. R-OH, Ar-OH, dimeric O-H str. 12 w. Ketones, C=O overtone C=O str. N-H str. , d. , d. 91 s. 11 m. 93 s. O-H str. free NH secondary amines N-H str. Sec. amides, free NH (trans) N-H str. Nitrites (R-O-N=O) overtones N=O str. Sec. ami des, free NH(cis) N-H str. 94 m.